THE EFFECT OF ASPECT RATIO ON MULTI-WALLED CARBON NANOTUBES FILLED EPOXY COMPOSITE AS ELECTRICALLY CONDUCTIVE ADHESIVE

  • M.M. Nasaruddin
  • S.H. Sheikh Md Fadzullah
  • G. Omar
  • Z. Mustafa
  • M. Ramli
  • M.Z. Akop
  • I.S. Mohamad
  • B. Çoşut

Abstract


Multi-walled carbon nanotubes (MWCNTs) filled epoxy resin is a type of Electrically Conductive Adhesive (ECA) that is used as interconnect materials in electronics application. Carbon-based conductive adhesive usually has inferior electrical conductivity to silver but mechanically superior in terms of its bonding integrity. The aim of this paper is to study the effect of aspect ratio on the electrical and mechanical properties of the composite adhesive. The aspect ratio of the two types of MWCNT fillers are of 55.5 and 1666.5. The filler loading for both MWCNTs varies from 5 wt.% to 12.7 wt.%. From the experimental study, the sheet resistance for the ECA with higher aspect ratio is approximately 4.42 kΩ/□ in comparison to only 44.86 kΩ/□ for the ECA with lower MWCNT aspect ratio. Morphological analysis of the ECA showed evidence of MWCNT distribution in the ECA with different diameter size. Nonetheless, the MWCNTs filled epoxy with lower aspect ratio exhibit higher shear strength with a maximum value of 8.08 MPa, in comparison to only 4.68 MPa to that of the ECA with higher MWCNTs aspect ratio, possibly due to the tendency in forming agglomeration of the MWCNT with smaller tube diameter, resulting in weaker interfacial strength.

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References

A. Eatemadi, D. Hadis, K. Hamzeh, K. Mohammad, Z. Nosratollah, A. Abolfazl, A. Mozhgan, H. Younes and W.J. Sang, “Carbon Nanotubes: Properties, Synthesis, Purification and Medical Applications”, Nanoscale Research Letters, vol. 9, no. 1, pp. 393-405, 2014.

H. Koga, T. Inui, I. Miyamoto, T. Sekiguchi, M. Nogi and K. Suganuma, “A High-Sensitivity Printed Antenna Prepared by Rapid Low-Temperature Sintering of Silver Ink”, RSC Advances, vol. 6, no. 87, pp. 84363-84368, 2016.

N. Xiong, M. Wang, H. Zhang, H. Xie, Y. Zhao, Y. Wang and J. Li, “Sintering Behavior and Effect of Silver Nanoparticles on the Resistivities of Electrically Conductive Adhesves Composed of Silver Flakes”, Journal of Adhesion Science and Technology, vol. 28, no. 24, pp. 2402-2415, 2014.

V. Ivanov and K.J. Wolter, “Degradations in the Silver-Filled Electrically Conductive Adhesive Joints to a Molybdenum Electrode after Environmental Ageing”, in International Symposium on Fundamentals of Electrical Engineering, Bucharest, Romania, 2014, pp. 1-5.

J.F. Zhu, H. Jin, M.B. Zhou and X.P. Zhang, “Electrical Property of Electrically Conductive Adhesives Filled with Micro-Sized Ag Flakes and Modified by Dicarboxylic Acids”, in 17th International Conference on Electronic Packaging Technology, Beijing, China, 2016, pp. 923-926.

I. Balberg, C.H. Anderson, S. Alexander and N. Wagner, “Excluded Volume and its Relation to the Onset of Percolation”, Physical Review B, vol. 30, no. 7, pp. 3933-3943, 1984.

R.M. Mutiso and I.W. Karen, “Electrical Properties of Polymer Nanocomposites Containing Rod-Like Nanofillers”, Progress in Polymer Science, vol. 40, no. 1, pp. 63-84, 2015.

M.R. Ayatollahi, S. Shadlou, M.M. Shokrieh and M. Chitsazzadeh, “Effect of multi-walled carbon nanotube aspect ratio on mechanical and Electrical Properties of Epoxy-Based Nanocomposites”, Polymer Testing, vol. 30, no. 5, pp. 548-556, 2011.

American Society for Testing and Materials International. (2011). Standard Test Method for Sheet Resistance of Thin Metallic Films with a Collinear Four Probe Array (ASTM F390 – 11) [Online]. Available: https://www.astm.org

American Society for Testing and Materials International. (2010). Standard Test Method for Apparent Shear Strength of Single-Lap-Joint Adhesively Bonded Metal Specimens by Tension Loading (Metal-to-Metal) (ASTM D1002 – 10) [Online]. Available: https://www.astm.org

I.A. Mir and D. Kumar, “Carbon nanotube-filled conductive adhesives for electronic applications”, Nanoscience Methods, vol. 1, no. 1, pp. 183-193, 2012.

J.Li, J.K. Lumpp, R. Andrews and D. Jacques, “Aspect Ratio and Loading Effects of Multiwall Carbon Nanotubes in Epoxy for Electrically Conductive Adhesives”, Journal of Adhesion Science and Technology, vol. 22, no. 14, pp. 1659-1671, 2012.

Y. Geng, M.Y. Liu, J. Li, X.M. Shi and J.K. Kim, “Effects of Surfactant Treatment on Mechanical and Electrical Properties of CNT/Epoxy Composites”, Composites: Part A, vol. 39, no. 12, pp. 1876-1883, 2008.

K.T. Hsiao, J. Alms and S.G. Advani, “Use of Epoxy-Multiwalled Carbon Nanotubes as Adhesives to Join Graphite Fibre Reinforced Polymer Composites”, Nanotechnology, vol. 14, no. 7, pp. 791-793, 2003.

M. Konstantakopoulu and G. Kotsikos, “Effect of MWCNT Filled Epoxy Adhesives on the Quality of Adhesively Bonded Joints”, Plastics, Rubber and Composites, vol. 45, no. 4, pp. 166-172, 2016.

A.S. Subramaniam, J.N. Tey, L. Zhang, B.H. Ng, S. Roy, J. Wei and X.M. Hu, “Synergistic Bond Strengthening in Epoxy Adhesives using Polydopamine/MWCNT Hybrids”, Polymer, vol. 82, no. 1, pp. 285-294, 2016.

P. Jojibabu, M. Jagannatham, P. Haridoss, G.D. Janaki Ram, A.P. Deshpande and S.R. Bakshi, “Effect of Different Carbon Nano-fillers on Rheological Properties and Lap Shear Strength of Epoxy Adhesive Joints”, Composites: Part A, vol. 82, no. 3, pp. 53-64, 2016.

How to Cite
Nasaruddin, M., Sheikh Md Fadzullah, S., Omar, G., Mustafa, Z., Ramli, M., Akop, M., Mohamad, I., & Çoşut, B. (1). THE EFFECT OF ASPECT RATIO ON MULTI-WALLED CARBON NANOTUBES FILLED EPOXY COMPOSITE AS ELECTRICALLY CONDUCTIVE ADHESIVE. Journal of Advanced Manufacturing Technology (JAMT), 13(1), 133-144. Retrieved from https://jamt.utem.edu.my/jamt/article/view/5258
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