EFFECT OF DEGUSSA P25 CONTENT ON THE DEPOSITION OF TiO2 COATING ON CERAMIC SUBSTRATE
Abstract
TiO2 coatings were deposited on unglazed ceramic tiles to study the property of its antimicrobial activity. Here, the effect of TiO2 nanoparticles content (Degussa P25) on the TiO2 coatings’ characteristics was investigated. TiO2 sol containing 25, 50, and 100 g/L Degussa P25 were deposited few times on ceramic tiles via sol-gel dip coating method and heat treated at 500°C. The coatings were analyzed using SEM and the phases were characterized using GAXRD. The results show that Degussa P25 content significantly influences the TiO2 coatings morphology and thickness. Increasing the Degussa P25 content led to a thicker and denser coating with different Degussa P25 content yielded different thickness at specific dipping time. 50 g/L of Degussa P25 was discovered as the maximum amount to be used for achieving good adherence coating on the ceramic tiles. Five dipping of TiO2 sol containing 50 g/L Degussa P25 was found appropriate to generate coating of continuous layer with average thickness of ~29 µm. The Degussa P25 content, however, shows insignificant effect on coating crystallinity.
Downloads
References
L.W.R. Sanborn, “The relation of surface contaminant to the transmission of disease”, American Journal of Public Health, vol. 58, no. 8, pp. 1278-1283, 1963.
S.D. Niederhãusern, M. Bondi and F. Bondioli, “Self-cleaning and antibacteric ceramic tile surface”, International Journal of Applied Ceramic Technology, vol. 10, no. 6, pp. 949-956, 2013.
S.-Q Sun, B. Sun, W. Zhang and D. Wang, “Preparation and antibacterial activity of Ag-TiO2 composite by liquid phase deposition (LPD) method”, Bulletin of Materials Science, vol. 31, no. 1, pp. 61-66, 2008.
M. Yao, J. Chen, C. Zhao and Y. Chen, “Photocatalytic activities of ion doped TiO2 thin films when prepared on different substrates”, Thin Solid Films, vol. 517, no. 21, pp. 5994-5999, 2009.
Z.M. Rosli, A.R. Nurhamizah and J.M. Juoi, “The effect of ceramic substrates surface roughness on the deposition of AgTiO2 coating”, Applied Mechanics and Materials, vol. 699, pp. 9-14 , 2014.
A. Shakeri, D. Yip, M. Badv, S.M. Imani, M. Sanjari and T.F. Didar, “Self-cleaning ceramic tiles produced via stable coating of TiO2 nanoparticles”, Materials, vol. 11, no. 6, pp. 1003-1018, 2018.
A.L. da Silva, M. Dondi and D. Hodza, “Self-cleaning ceramic tiles coated with nb2o5-doped-TiO2 nanoparticles ”, Ceramics International, vol. 43, no. 15, pp. 11986-11991, 2017.
S. Ke, X. Cheng, Q. Wang, Y. Wang and Z. Pan, “Preparation of a photocatalytic TiO2/ZnTiO3 coating on glazed ceramic tiles”, Ceramics International, vol. 40, no. 6, pp. 8891-8895, 2014.
P. Sooksaen, N. Saowaros, K. Ngamkaruhasereethorn and A. Pringkasemchai, “Photocatalytic degradation study of titania sol-gel coated on commercial unglazed ceramic tiles”, Key Engineering Materials, vol. 751, pp. 819-824, 2017.
M. Hasmaliza, H.S. Foo and K. Mohd, “Anatase as antibacterial material in ceramic tiles”, Procedia Chemistry, vol. 19, pp. 828-834, 2016.
F. Bondioli, R. Taurino and A. M. Ferrari, “Functionalization of ceramic tile surface by sol-gel technique”, Journal of Colloid and Interface Science, vol. 334, no. 2, pp. 195-201, 2009.
T. Sreethawong, S. Ngamsinlapasathian and S. Yoshikawa, “Positive role of incorporating P-25 TiO2 to mesoporous-assembled tio2 thin films for improving photocatalytic dye degradation efficiency”, Journal of Colloid and Interface Science, vol. 430, pp. 184-192, 2014.
J. Kim, A. Sotto, J. Chang, D. Nam, A. Boromand and B.V. Bruggen, “Embedding TiO2 nanoparticles versus surface coating by layer-by-layer deposition on nanoporous polymeric films”, Microporous and Mesoporous Materials, vol. 173, pp. 121-128, 2013.
Y. Chen and D.D. Dionysiou, “TiO2 photocatalytic films on stainless steel: the role of degussa P-25 in modified sol-gel methods”, Applied Catalysis B: Environmental, vol. 62, no. 3-4, pp. 255-264, 2006.
G. Balasubramanian, D.D. Dionysiou, M.T. Suidan, I. Baudin and J.-M. Laine, “Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water”, Applied Catalysis B: Environmental, vol. 47, no. 2, pp. 73-84, 2004.
L. Lopez, W.A. Daoud, D. Dutta, B.C. Panther and T.W. Turney, “Effect of substrate on surface morphology and photocatalysis of large-scale TiO2 films”, Applied Surface Science, vol. 265, pp. 162-168,